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F. (1981). The temporal and spatial distribution of tropospheric nitrous oxide, J. Geophys. Res. 86, C 8, 7185. 736cm- 1 17 m bar 296K 96 m Modu l. amp!. 707cm- 1 T DL CURRE NT - WAVENUMBER Fig. 9 a NH . 2 ppbv as derived from spectrum (A) and the calibratLon procedure described. CO 2 mixing ratio (340 ppmv) and other parameters as for the experimental spectrum. > Z v J~ v o ::£ a: '" :t: o 13 mbar 296K ~Om V o Modul. 9o<",o, N,O : 300ppbv If) H,~ : Z hl lppbv WAVENUMBER Fig. 2 - Computer generated second harmonic spectrum.
The system has been developed under contract of the Gennan Federal Environmental lIgency, with the objective to detect mean concentrations of this pollutant on a routine basis /1/. The system can be used for day arrl night operatirn. i::M detection limits caribined with high response time can be aChieved. After rrodifications the system can also be used for the detection of other pollutants with sufficient strong absorption lines like ID, ID2' NH3 etc. \S)" using a lead salt laser diode as light source /2/.
The list oontains many hydrocarbons like ethylene (C2HIt) which is one of the major oonstituents of car exhaust gases, but also species involved in the photochemical smog formation like PAN. 12C1602 _ LaSer 12C160 - Laser Nitric oxide Nitrogen dioxide Peroxiacetylnitrate (PAN) Formaldehyde Ethylene Propylene 1,3-Butadiene Benzene Ammonia Hydrogen nitrate ID ID2 CH30)3ID2 H200 C2HIt C3H6 Clt H6 C6 H6 NH3 HID3 -46- Ethylene Propylene 1,3-Butadiene Benzene Toluene Trichloroethylene Perchloroethylene Ozone Ammonia Phosgene C2HIt C3 H6 Clt H6 C6H6 C7Ha C2HCl 3 C2Cl it 03 NH3 Cl2CO 2.