By J. C. Bevington (auth.)
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Extra resources for Fortschritte Der Hochpolymeren-Forschung
It probably does not influence the optical properties but may accelerate the reaction, for it has been found that ether cleavage reactions of the type ROCH~R + H X - + ROH + XCH2R, are markedly accelerated in solvents of low dielectric constant b y either soluble or insoluble inorganic salts. The catalytic activity of the salts seems to lie in the ability of their ionic dipoles to provide a suitable site for the heterolytic fission (29). The experiments with optically active 1-propylene oxide have established clearly the need to control the polymer symmetry if crystalline products are to be obtained from monomers which contain or can yield an asymmetric centre.
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Soc. 1956, 547. 20. EASTHAM, A. : J. Amer. chem. Soc. 78, 6040 (1956). 21. , W. C. E. HIGGII~SON, P. L~VESLEY and K. J. TAYLOR: J. chem. Soc. 1959, 1338. , W. C. E. HIGGII~SON and G. T. MERRALL: J. chem. Soc. 1959, 1345. 22. , and M. HATA~O: t(ogyo Kagaku Zasshi 60, 1585 (1957); C. A. 53, 18, 933 (1959). 23. RTIES,E. L. : U. S. P. 2,856,370 (1958). Fortschr. ,Bd. M. EASTHAM: Some Aspects of the Polymerization of Cyclic Ethers 24. " GAYLORD,N. , and H. F. MARK: Interscience, page 305. New York 1959.