By J. E. Macintyre (auth.), J. E. Macintyre (eds.)
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Additional resources for Dictionary of Organometallic Compounds: Second Supplement
USSR (Engl. ), 1052 (synth) Balimann, G. et ai, Helv. Chirn. Acta, 1975,58, 1913 (crnr) Balimann, G. et ai, J. Magn. 159 t> Esters cause skin burns, and are throat and lung irritants Me ester: Methyl dibutylarsinite. Dibutylmethoxyarsine. 186 Liq. 06. BPl2 85-87°. 4653. Et ester: Ethyl dibutylarsinite. Dibutylethoxyarsine. 213 Liq. 03. BplO 89-91°. 4613. Butyl ester: Butyl dibutylarsinite. Butoxydibutylarsine. 187 Liq. 01. BplO 117-118°. 4627. 381 Liq. BP7 164-167°. 634 Liq. J 2. l 48-49°. 5096.
J. et aI, J. Chern. , Chem. , Z. Anorg. AI/g. , J. Organornet. 942 Gas. ). t. At 200° for 6 hrs. yields CHF3. Aq. alkali yields CHF3. J. et aI, J. Chem. , Can. J. G. et aI, J. Chem. Soc. C. et aI, [norg. , 1967,6,1450 (ms) Burger, H. et aI, Spectrochim. 838 Liq. 5°. 398. Aq. alkali gives CHF3. J. et 01, J. Chern. , Z. Anorg. AUg. 941 Rapidly cleaved in hot H 20 ->- As 20 3. Alkali, HN0 3, H 2S or KI ->- CHF3. Yields isolable di-Ag salt. 387 Liq. 8p 46°, BP294 22°, BPlO3 0°. 351. t. Aq. alkali ->- CHF3.
J. Am. Chern. Soc .. A. et ai, Izv. Akad. Nauk SSSR, Ser. , 1972,1612 (Eng/. transl. p. 585 Solid. Mp 176-178°. F. et aI, Zh. Obshch. , 1966,36, 2024; 1. Gen. Chern. USSR (Engl. 123 Volatile solid. Mp 33-35°. BP3 153°. Darkens on expo to light. Morgan. T. el al. 1. Am. Chern. Soc .. 1947,69,932 (synlh. 140 Me ester: [24582-54-5]. Methyl diphenylarsinite. Methoxydiphenylarsine. 167 Liq. 27. Bp27 175-178°. 6070. Et ester: [24582-55-6]. Ethyl diphenylarsinite. Ethoxydiphenylarsine. 194 Liq. 25. BplO 160°.