By Stanley M. Roberts, Ivan V. Kozhevnikov, Eric Derouane(eds.)
The chemist has an unlimited variety of high-tech catalysts to exploit whilst operating in fine chemical synthesis however the catalysts are quite often challenging to exploit and require either time, ability and event to address competently. The Catalysts for positive Chemical Synthesis series contains confirmed and demonstrated methods which provide a special diversity assets for chemists who paintings in natural chemistry.
"... of serious worth to artificial natural chemists..." (The Chemists, summer season 2003)
quantity three within the sequence specializes in catalysts for carbon-carbon bond formation and offers useful and detailed protocols on the way to use subtle catalysts via the "inventors" and "developers" who created them. The combination of protocols and overview commentaries is helping the reader to simply and quickly understand and use the hot high-tech catalysts.Content:
Chapter 1 concerns of business wonderful Chemical Synthesis (pages 1–12): Mark W. Hooper
Chapter 2 Alkylation and Allylation adjoining to a Carbonyl workforce (pages 13–33): Fumitoshi Kakiuchi, Satoshi Ueno, Naoto Chatani, Michael North, Jose A. Fuentes, Barry Lygo and Benjamin I. Andrews
Chapter three uneven Alkylation or Amination of Allylic Esters (pages 35–57): Maria Zablocka, Marek Koprowski, Jean?Pierre Majoral, Mathieu Achard, Gerard Buono, Jerome Bayardon, Denis Sinou, Matthias Lotz, Gernot Kramer, Katja Tappe, Paul Knochel, Pierluigi Barbaro, Claudio Bianchini, Giuliano Giambastiani and Antonio Togni
Chapter four Suzuki Coupling Reactions (pages 59–90): Ana S. Abreu, Paula M. T. Ferreira, Maria?Joao R. P. Queiroz, Jie Wu, Lisha Wang, Reza Fathi, Zhen Yang, Ramon E. Huertas, John A. Soderquist, Tatsuo Ishiyama, Norio Miyaura, Bin Tao, David W. Boykin, Colin Baillie, Lijin Xu, Jianliang Xiao, Matthew L. Clarke, J. Derek Woollins, Nicholas Marion, Oscar Navarro, Roy A. Kelly and Steven P. Nolan
Chapter five Heck Coupling Reactions (pages 91–112): Peter Nilsson, Mats Larhed, Lijin Xu, Jun Mo, Jianliang Xiao, Tim G. Kilroy, Yvonne M. Malone and Patrick J. Guiry
Chapter 6 Sonogashira Coupling Reactions (pages 113–125): Anupama Datta, Herbert Plenio, Chih?An Lin and Fen?Tair Luo
Chapter 7 Cross?Coupling Reactions (pages 127–153): Jun Terao, Nobuaki Kambe, Luis A. Sarandeses, Jose Perez Sestelo, Bryan A. Frieman, Bruce H. Lipshutz, John Mancuso, Masahiro Yoshida and Mark Lautens
Chapter eight Regioselective or uneven 1,2?Addition to Aldehydes (pages 155–168): Kui?Thong Tan, Shu?Sin Chng, Hin?Soon Cheng, Teck?Peng Loh, Jens Rudolph, Carsten Bolm, Marco Lombardo, Sebastiano Licciulli, Stefano Morganti and Claudio Trombini
Chapter nine Olefin Metathesis Reactions (pages 169–180): Syuzanna Harutyunyan, Anna Michrowska, Karol Grela, Stephen J. Connon, Aideen M. Dunne, Siegfried Blechert, G. Bhaskar and B. Venkateswara Rao
Chapter 10 Cyclisation Reactions (pages 181–200): Jaime Blanco?Urgoiti, Gema Dominguez, Javier Perez?Castells, Ligang Zhao, Xiyan Lu, Minsheng He, Aiwen Lei, Xumu Zhang, Hiroshi Shinokubo, Koichiro Oshima, Antonio Rosales, Juan M. Cuerva and Enrique Oltra
Chapter eleven uneven Aldol and Michael Reactions (pages 201–223): Masakatsu Shibasaki, Shigeki Matsunaga, Naoya Kumagai, Zhuo Tang, Liu?Zhu Gong, Ai?Qiao Mi, Yao?Zhong Jiang, Masahito Watanabe, Kunihiko Murata and Takao Ikariya
Chapter 12 Stereoselective Hydroformylation, Carbonylation and Carboxylation Reactions (pages 225–250): Bernhard Breit, Martin Wills, Simon W. Breeden, Stefania Cserepi?Szucs, Jozsef Bakos, C. Ramesh, Y. Kubota, Y. Sugi, Tomoko Matsuda, Tadao Harada, Toru Nagasawa and Kaoru Nakamura
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Additional info for Catalysts for Fine Chemical Synthesis: Metal Catalysed Carbon-Carbon Bond-Forming Reactions, Volume 3
1] One of the most important factors in the success of these reactions involves chelation-assistance by a heteroatom. Thus, the co-ordination of the heteroatom to the metal, brings the metal closer to the carbon-hydrogen bond and stabilises the thermally unstable C-M-H species formed by the oxidative addition of a carbon-hydrogen bond to a low valent transition metal complex. In addition, the use of the chelation-assistance leads to a high regioselectivity, an essential factor in organic synthesis.
Toluene ALKYLATION AND ALLYLATION ADJACENT TO A CARBONYL GROUP 17 and triethoxyvinylsilane are removed under reduced pressure. After almost all volatile materials are removed, the other half of the reaction mixture is transferred to the flask. The reaction vessel is rinsed with two 5 mL portions of toluene; the rinses are also transferred to the flask. The volatile materials of the combined reaction mixture and rinses are evaporated. 2 mmHg. 56 Hz, 1H, ArH). 28. 448 g, 4 mmol Toluene, mL One One One One One 10-mL two-necked, round-bottomed flask magnetic stirring bar reflux condenser nitrogen inlet tube sealed with a rubber septum 10-mL round-bottomed flask Procedure The apparatus, consisting of 10-mL two-necked flask equipped with a reflux condenser connected to a nitrogen line, a rubber septum, and a magnetic stirring bar, is flame dried under a flow of nitrogen.
2]octane bromide . 3 Synthesis of (2S)-tert-butyl 2-amino-4-bromopent-4-enoate . . . . . 4 Conclusion . . . . . . . . . . . . . . . . . . . . . . References . . . . . . . . . . . . . . . . . . . . . . . . ... 27 ... 28 . . 29 31 32 33 . . . . Catalysts for Fine Chemical Synthesis, Vol. 3, Metal Catalysed Carbon-Carbon Bond-Forming Reactions Edited by S. M. Roberts, J. Xiao, J. Whittall, and T.  One of the most important factors in the success of these reactions involves chelation-assistance by a heteroatom.